Remove New Outlook / Legacy Outlook toggle in Outlook for Mac
Quit Outlook and run:
defaults write com.microsoft.Outlook EnableNewOutlook -int 0
Before:

After:

See also these links on the dangers of New Outlook and instructions for disabling in Windows.
Sources
Is the toggle for "New Outlook" on macOS no longer hidden by default?
Set the availability and default position of the New Outlook switch:
Category Details Domain com.microsoft.Outlook Key EnableNewOutlook Data Type Integer Possible values 0 = Switch hidden
1 = Switch displayed, default off
2 = Switch displayed, default on (default)
3 = New Outlook enabled with switch hiddenRequires Configuration Profile No Availability 16.38
❧ 2025-12-09